Pd/C-catalyzed aerobic oxidative esterification of alcohols and aldehydes: a highly efficient microwave-assisted green protocol

نویسندگان

  • Marina Caporaso
  • Giancarlo Cravotto
  • Spyros Georgakopoulos
  • George Heropoulos
  • Katia Martina
  • Silvia Tagliapietra
چکیده

We herein describe an environmentally friendly microwave-assisted oxidative esterification of alcohols and aldehydes in the presence of molecular oxygen and a heterogeneous catalysis (Pd/C, 5 mol %). This efficient and ligandless conversion procedure does not require the addition of an organic hydrogen acceptor. The reaction rate is strongly enhanced by mild dielectric heating. Furthermore, it is a versatile green procedure which generally enables the isolation of esters to be carried out by simple filtration in almost quantitative yields.

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عنوان ژورنال:

دوره 10  شماره 

صفحات  -

تاریخ انتشار 2014